Intermolecular Forces and Properties unit test
A test on this unit alone, marked as a percentage and a letter grade — for the test your class is actually sitting, rather than for May. Answer everything, then submit once: seeing the answer to question 3 before attempting question 4 makes the final percentage meaningless.
Real gas deviation direction
Boiling point and IMF strength
Partial pressure and Dalton's law
Kinetic molecular theory assumptions
Maxwell-Boltzmann distribution
Molarity
Surface tension and viscosity
Distillation
Solubility and "like dissolves like"
Chromatography
Beer-Lambert law
Effusion and Graham's law
Short answer 1. Define or explain: London dispersion forces
3 ptsShort answer 2. Define or explain: Hydrogen bonding
3 ptsShort answer 3. Define or explain: Comparing boiling points correctly
3 ptsShort answer 4. Define or explain: Why intermolecular forces are weaker than bonds
3 ptsFree response
10 ptsThis course has no free-response prompt tagged to this unit, so one from elsewhere in the course is used. It is still worth writing — the skill transfers.
A student titrates 25.00 mL of a solution of an unknown monoprotic weak acid HA with 0.150 M NaOH. The equivalence point occurs after 32.00 mL of titrant has been added. When 16.00 mL of NaOH has been added, the measured pH is 4.65.
Calculate the moles of HA originally present and its initial molarity.
Determine the Ka of HA, and explain why the pH at 16.00 mL gives this information directly.
Predict whether the pH at the equivalence point is above, below, or equal to 7.00, and justify your answer with a chemical equation.
Explain which of phenolphthalein (transition range 8.3–10.0) or methyl red (transition range 4.4–6.2) is the better indicator for this titration.
Describe the effect on the calculated molarity of HA if the student had rinsed the burette with distilled water and left it wet before filling it with NaOH.