Intermolecular Forces and Properties unit test
A test on this unit alone, marked as a percentage and a letter grade — for the test your class is actually sitting, rather than for May. Answer everything, then submit once: seeing the answer to question 3 before attempting question 4 makes the final percentage meaningless.
Distillation
Dipole-dipole forces
Maxwell-Boltzmann distribution
Ideal gas law
Hydrogen bonding
Effusion and Graham's law
Molarity
Kinetic molecular theory assumptions
Vapor pressure
Surface tension and viscosity
Solubility and "like dissolves like"
Real gas deviation direction
Short answer 1. Define or explain: Why intermolecular forces are weaker than bonds
3 ptsShort answer 2. Define or explain: Capillary action
3 ptsShort answer 3. Define or explain: Ion-dipole forces
3 ptsShort answer 4. Define or explain: Chromatography
3 ptsFree response
10 ptsThis course has no free-response prompt tagged to this unit, so one from elsewhere in the course is used. It is still worth writing — the skill transfers.
A 0.750 g sample of impure calcium carbonate is treated with excess hydrochloric acid: CaCO₃(s) + 2 HCl(aq) → CaCl₂(aq) + H₂O(l) + CO₂(g). The CO₂ produced is collected over water at 25 °C, where the total pressure is 755 torr and the collected volume is 155 mL. The vapor pressure of water at 25 °C is 23.8 torr.
Calculate the partial pressure of CO₂ in atmospheres.
Calculate the number of moles of CO₂ collected.
Calculate the mass percent of CaCO₃ in the original sample.
Explain the direction in which the calculated mass percent would be biased if the student forgot to subtract the water vapor pressure.
Describe one experimental observation that would confirm the HCl was truly present in excess.