Atomic Structure & Properties unit test
A test on this unit alone, marked as a percentage and a letter grade — for the test your class is actually sitting, rather than for May. Answer everything, then submit once: seeing the answer to question 3 before attempting question 4 makes the final percentage meaningless.
Average atomic mass
Molar mass
Isotopes
Mole and Avogadro's number
Mass spectrometry
Shielding
Effective nuclear charge (Zeff)
Reading a PES spectrum
Atomic radius trend
Percent composition
Ionization energy trend
Electron configuration
Short answer 1. Define or explain: Why the first ionization energy of oxygen is below nitrogen
3 ptsShort answer 2. Define or explain: Photon energy
3 ptsShort answer 3. Define or explain: Electronegativity
3 ptsShort answer 4. Define or explain: Photoelectron spectroscopy
3 ptsFree response
10 ptsThis course has no free-response prompt tagged to this unit, so one from elsewhere in the course is used. It is still worth writing — the skill transfers.
A student titrates 25.00 mL of a solution of an unknown monoprotic weak acid HA with 0.150 M NaOH. The equivalence point occurs after 32.00 mL of titrant has been added. When 16.00 mL of NaOH has been added, the measured pH is 4.65.
Calculate the moles of HA originally present and its initial molarity.
Determine the Ka of HA, and explain why the pH at 16.00 mL gives this information directly.
Predict whether the pH at the equivalence point is above, below, or equal to 7.00, and justify your answer with a chemical equation.
Explain which of phenolphthalein (transition range 8.3–10.0) or methyl red (transition range 4.4–6.2) is the better indicator for this titration.
Describe the effect on the calculated molarity of HA if the student had rinsed the burette with distilled water and left it wet before filling it with NaOH.