Atomic Structure & Properties unit test
A test on this unit alone, marked as a percentage and a letter grade — for the test your class is actually sitting, rather than for May. Answer everything, then submit once: seeing the answer to question 3 before attempting question 4 makes the final percentage meaningless.
Average atomic mass
Photon energy
Shielding
Electronegativity
Molar mass
Isotopes
Ionic radius
Why the first ionization energy of oxygen is below nitrogen
Mole and Avogadro's number
Empirical vs molecular formula
Percent composition
Valence electrons
Short answer 1. Define or explain: Absorption and emission spectra
3 ptsShort answer 2. Define or explain: Mass spectrometry
3 ptsShort answer 3. Define or explain: Effective nuclear charge (Zeff)
3 ptsShort answer 4. Define or explain: Ionization energy trend
3 ptsFree response
10 ptsThis course has no free-response prompt tagged to this unit, so one from elsewhere in the course is used. It is still worth writing — the skill transfers.
A 0.750 g sample of impure calcium carbonate is treated with excess hydrochloric acid: CaCO₃(s) + 2 HCl(aq) → CaCl₂(aq) + H₂O(l) + CO₂(g). The CO₂ produced is collected over water at 25 °C, where the total pressure is 755 torr and the collected volume is 155 mL. The vapor pressure of water at 25 °C is 23.8 torr.
Calculate the partial pressure of CO₂ in atmospheres.
Calculate the number of moles of CO₂ collected.
Calculate the mass percent of CaCO₃ in the original sample.
Explain the direction in which the calculated mass percent would be biased if the student forgot to subtract the water vapor pressure.
Describe one experimental observation that would confirm the HCl was truly present in excess.