Equilibrium unit test
A test on this unit alone, marked as a percentage and a letter grade — for the test your class is actually sitting, rather than for May. Answer everything, then submit once: seeing the answer to question 3 before attempting question 4 makes the final percentage meaningless.
Le Châtelier's principle
Common ion effect
Effect of a catalyst on equilibrium
Magnitude of K
Q vs K reasoning on a graph
Solubility product Ksp
Effect of temperature on K
Small-x approximation
Relating K for reversed and scaled reactions
ICE table
pH effect on solubility
Dynamic equilibrium
Short answer 1. Define or explain: Adding an inert gas at constant volume
3 ptsShort answer 2. Define or explain: Effect of volume change
3 ptsShort answer 3. Define or explain: Kc and Kp relationship
3 ptsShort answer 4. Define or explain: Reaction quotient Q
3 ptsFree response
4 ptsStrontium hydroxide dissolves in water according to the following equation: Sr(OH)2(s) ⇌ Sr2+(aq) + 2 OH−(aq) Ksp = [Sr2+][OH−]² A student draws a particulate diagram to represent the ions present in an aqueous solution of Sr(OH)2, with water molecules intentionally omitted. The diagram shows 4 Sr2+ ions and 5 OH− ions. The student then prepares a saturated solution by adding excess Sr(OH)2(s) to distilled water and stirring until no more solid dissolves, and determines that [Sr2+] = 0.043 M in the solution.
(a) Identify the error in the student’s drawing.
(b)(i) Calculate the value of [OH−] in the saturated solution.
(b)(ii) Calculate the value of Ksp for Sr(OH)2.
(c) The student prepares a second saturated solution of Sr(OH)2 in aqueous 0.10 M Sr(NO3)2 instead of in water. Will the value of [OH−] in the second solution be greater than, less than, or equal to the value in the first solution? Justify your answer. (Assume constant temperature.)